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In the “S 4 Mechanism” interpretation, formation of a high oxidation state metal oxo intermediate is invoked in the S 3 → S 4 step either as low-spin Mn V =O or a high-spin oxyl, Mn IV -O · , which is sufficiently electrophilic to forge an O-O bond followed by O 2 release

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Nonetheless, the most updated literature reports that β-carotene supplementation or elevated blood β-carotene levels may increase all-cause mortality and CVD risk [147, 148]